日本語フィールド
著者：Kodama, Shintaro; Yamamoto, Yuki; Kobiki, Yohsuke; Matsubara, Hitomi; Tran, Cong Chi; Kawaguchi, Shin Ichi; Nomoto, Akihiro; Ogawa, Akiya題名：Transition-metal-catalyzed diarylation of isocyanides with triarylbismuthines for the selective synthesis of imine derivatives発表情報：Materials 巻: 14 号: 15 ページ: - キーワード：概要：The transition-metal-catalyzed diarylation of isocyanides with triarylbismuthines was investigated in detail, and rhodium catalysts such as [RhCl(nbd)]2 were found to selectively afford N-alkyl diaryl ketimines. On the other hand, palladium-catalyzed diarylation proceeded with the in-corporation of two molecules of isocyanide, preferentially yielding N,N’-dialkyl or N,N’-diaryl α-diimines. In addition, a cascade synthesis of 2,3-diarylquinoxalines starting from the palladium-catalyzed diarylation of isocyanides with triarylbismuthines was successfully achieved.抄録：英語フィールド
Author：Kodama, Shintaro; Yamamoto, Yuki; Kobiki, Yohsuke; Matsubara, Hitomi; Tran, Cong Chi; Kawaguchi, Shin Ichi; Nomoto, Akihiro; Ogawa, AkiyaTitle：Transition-metal-catalyzed diarylation of isocyanides with triarylbismuthines for the selective synthesis of imine derivativesAnnouncement information:Materials Vol: 14 Issue: 15 Page: - An abstract：The transition-metal-catalyzed diarylation of isocyanides with triarylbismuthines was investigated in detail, and rhodium catalysts such as [RhCl(nbd)]2 were found to selectively afford N-alkyl diaryl ketimines. On the other hand, palladium-catalyzed diarylation proceeded with the in-corporation of two molecules of isocyanide, preferentially yielding N,N’-dialkyl or N,N’-diaryl α-diimines. In addition, a cascade synthesis of 2,3-diarylquinoxalines starting from the palladium-catalyzed diarylation of isocyanides with triarylbismuthines was successfully achieved.