日本語フィールド
著者：Tran, Dat Phuc; Sato, Yuki; Yamamoto, Yuki; Kawaguchi, Shin Ichi; Kodama, Shintaro; Nomoto, Akihiro; Ogawa, Akiya題名：Highly regio- And stereoselective phosphinylphosphination of terminal alkynes with tetraphenyldiphosphine monoxide under radical conditions発表情報：Beilstein Journal of Organic Chemistry 巻: 17 ページ: 866 - 872キーワード：概要：The homolytic cleavage of the P (O)-P bond in tetraphenyldiphosphine monoxide simultaneously provides both pentavalent and trivalent phosphorus-centered radicals with different reactivities. The method using V-40 as an initiator is successfully investigated for the regio- and stereoselective phosphinylphosphination of terminal alkynes giving the corresponding trans-isomers of 1-diphenylphosphinyl-2-diphenylthiophosphinyl-1-alkenes in good yields. The protocol can be applied to a wide variety of terminal alkynes including both alkyl- and arylalkynes. V III抄録：英語フィールド
Author：Tran, Dat Phuc; Sato, Yuki; Yamamoto, Yuki; Kawaguchi, Shin Ichi; Kodama, Shintaro; Nomoto, Akihiro; Ogawa, AkiyaTitle：Highly regio- And stereoselective phosphinylphosphination of terminal alkynes with tetraphenyldiphosphine monoxide under radical conditionsAnnouncement information:Beilstein Journal of Organic Chemistry Vol: 17 Page: 866 - 872An abstract：The homolytic cleavage of the P (O)-P bond in tetraphenyldiphosphine monoxide simultaneously provides both pentavalent and trivalent phosphorus-centered radicals with different reactivities. The method using V-40 as an initiator is successfully investigated for the regio- and stereoselective phosphinylphosphination of terminal alkynes giving the corresponding trans-isomers of 1-diphenylphosphinyl-2-diphenylthiophosphinyl-1-alkenes in good yields. The protocol can be applied to a wide variety of terminal alkynes including both alkyl- and arylalkynes. V III