日本語フィールド
著者：Dong, Chun Ping; Nakamura, Kentaro; Taniguchi, Toshihide; Mita, Soichiro; Kodama, Shintaro; Kawaguchi, Shin Ichi; Nomoto, Akihiro; Ogawa, Akiya; Mizuno, Takumi題名：Synthesis of Aryl Iodides from Arylhydrazines and Iodine発表情報：ACS Omega 巻: 3 号: 8 ページ: 9814 - 9821キーワード：概要：© 2018 American Chemical Society. A metal-and base-free method is developed for the synthesis of aryl iodides from arylhydrazine hydrochlorides and iodine. A wide variety of aryl iodides can be conveniently synthesized by an equimolar reaction of arylhydrazine hydrochlorides and I2 in dimethyl sulfoxide at 60 °C for 6 h. In the iodination step, arylhydrazines are oxidized by iodine to form arenediazonium salts, which undergo single-electron transfer from iodide anion to give aryl and iodine radicals; subsequent combination of them affords the corresponding aryl iodides.抄録：英語フィールド
Author：Dong, Chun Ping; Nakamura, Kentaro; Taniguchi, Toshihide; Mita, Soichiro; Kodama, Shintaro; Kawaguchi, Shin Ichi; Nomoto, Akihiro; Ogawa, Akiya; Mizuno, TakumiTitle：Synthesis of Aryl Iodides from Arylhydrazines and IodineAnnouncement information:ACS Omega Vol: 3 Issue: 8 Page: 9814 - 9821An abstract：© 2018 American Chemical Society. A metal-and base-free method is developed for the synthesis of aryl iodides from arylhydrazine hydrochlorides and iodine. A wide variety of aryl iodides can be conveniently synthesized by an equimolar reaction of arylhydrazine hydrochlorides and I2 in dimethyl sulfoxide at 60 °C for 6 h. In the iodination step, arylhydrazines are oxidized by iodine to form arenediazonium salts, which undergo single-electron transfer from iodide anion to give aryl and iodine radicals; subsequent combination of them affords the corresponding aryl iodides.