日本語フィールド
著者：Sato, Yuki; Nishimura, Misaki; Kawaguchi, Shin ichi; Nomoto, Akihiro; Ogawa, Akiya題名：Reductive Rearrangement of Tetraphenyldiphosphine Disulfide To Trigger the Bisthiophosphinylation of Alkenes and Alkynes発表情報：Chemistry - A European Journal 巻: 25 号: 27 ページ: 6797 - 6806キーワード：概要：© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim The facile synthesis of organophosphorus compounds is of great importance for the development of new synthetic methods by using air-stable sources of phosphorus. In this respect, a synthetic method that is based on a reductive rearrangement and is capable of converting air-stable pentavalent phosphorus compounds into reactive trivalent phosphorus compounds is a powerful tool. Tetraphenyldiphosphine disulfide, which is a shelf-stable solid, was the focus of this study, and it was shown to undergo reductive rearrangement to trigger the bisthiophosphinylation of a variety of alkenes, such as terminal, cyclic, internal, and branched alkenes, 1,3-dienes, and terminal alkynes when exposed to light without any catalyst, base, or additive.抄録：英語フィールド
Author：Sato, Yuki; Nishimura, Misaki; Kawaguchi, Shin ichi; Nomoto, Akihiro; Ogawa, AkiyaTitle：Reductive Rearrangement of Tetraphenyldiphosphine Disulfide To Trigger the Bisthiophosphinylation of Alkenes and AlkynesAnnouncement information:Chemistry - A European Journal Vol: 25 Issue: 27 Page: 6797 - 6806An abstract：© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim The facile synthesis of organophosphorus compounds is of great importance for the development of new synthetic methods by using air-stable sources of phosphorus. In this respect, a synthetic method that is based on a reductive rearrangement and is capable of converting air-stable pentavalent phosphorus compounds into reactive trivalent phosphorus compounds is a powerful tool. Tetraphenyldiphosphine disulfide, which is a shelf-stable solid, was the focus of this study, and it was shown to undergo reductive rearrangement to trigger the bisthiophosphinylation of a variety of alkenes, such as terminal, cyclic, internal, and branched alkenes, 1,3-dienes, and terminal alkynes when exposed to light without any catalyst, base, or additive.