日本語フィールド
著者：Saga, Yuta; Saga, Yuta; Mino, Yuka; Kawaguchi, Shin ichi; Han, Daoqing; Ogawa, Akiya; Han, Li Biao題名：The PMe3-catalyzed addition of enantiomerically pure (−)-MenthylO(Ph)P(O)H to electron-deficient alkenes: an efficient way for the preparation of P-stereogenic compounds発表情報：Tetrahedron Asymmetry 巻: 28 号: 1 ページ: 8489キーワード：概要：© 2016 Elsevier Ltd A variety of P-stereogenic organophosphorus compounds can be readily prepared by stereoretentive addition. The PMe 3 -catalyzed addition of optically active (−)MenthylO(Ph)P(O)H compounds to electron deficient alkenes occur stereospecifically, to produce the corresponding P-stereogenic adducts in high yields. By simply removing the volatiles under vacuum, spectroscopically pure products can be obtained. The present method provides a salt-free clean process for the preparation of P-chiral organophosphorus compounds.抄録：英語フィールド
Author：Saga, Yuta; Saga, Yuta; Mino, Yuka; Kawaguchi, Shin ichi; Han, Daoqing; Ogawa, Akiya; Han, Li BiaoTitle：The PMe3-catalyzed addition of enantiomerically pure (−)-MenthylO(Ph)P(O)H to electron-deficient alkenes: an efficient way for the preparation of P-stereogenic compoundsAnnouncement information:Tetrahedron Asymmetry Vol: 28 Issue: 1 Page: 8489An abstract：© 2016 Elsevier Ltd A variety of P-stereogenic organophosphorus compounds can be readily prepared by stereoretentive addition. The PMe 3 -catalyzed addition of optically active (−)MenthylO(Ph)P(O)H compounds to electron deficient alkenes occur stereospecifically, to produce the corresponding P-stereogenic adducts in high yields. By simply removing the volatiles under vacuum, spectroscopically pure products can be obtained. The present method provides a salt-free clean process for the preparation of P-chiral organophosphorus compounds.