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Recovery of Sb(V) using a functional-ligand-containing porous hollow-fiber membrane prepared by radiation-induced graft polymerization.

発表形態:
原著論文
主要業績:
主要業績
単著・共著:
共著
発表年月:
2006年
DOI:
会議属性:
査読:
有り
リンク情報:

日本語フィールド

著者:
Kawakita, Hidetaka; Uezu, Kazuya; Tsuneda, Satoshi; Saito, Kyoichi; Tamada, Masao; Sugo, Takanobu.
題名:
Recovery of Sb(V) using a functional-ligand-containing porous hollow-fiber membrane prepared by radiation-induced graft polymerization.
発表情報:
Hydrometallurgy 巻: 2006 ページ: 190-196
キーワード:
概要:
抄録:
A ligand-contg. porous membrane was prepd. by radiation-induced graft polymn. of an epoxy-group-contg. monomer of glycidyl methacrylate onto a polyethylene porous hollow-fiber membrane and by subsequent conversion of the epoxy group to an N-methylglucamino (NMG) group at a d. of 0.78 mmol/g of the membrane. Sb(V) soln. was permeated through the NMG-ligand-contg. porous hollow-fiber membrane. Optimum pH for Sb(V) recovery was 3.0. Breakthrough curves of Sb(V) overlapped irresp. of residence times of Sb(V) in the membrane, due to negligible diffusional mass-transfer resistance. Maximum amt. of Sb(V) adsorbed was 130 mg/g-membrane, which was equiv. to 1.3 binding molar ratio. Repeated usage of the membrane for adsorption and elution was possible.

英語フィールド

Author:
Kawakita, Hidetaka; Uezu, Kazuya; Tsuneda, Satoshi; Saito, Kyoichi; Tamada, Masao; Sugo, Takanobu.
Title:
Recovery of Sb(V) using a functional-ligand-containing porous hollow-fiber membrane prepared by radiation-induced graft polymerization.
Announcement information:
Hydrometallurgy Vol: 2006 Page: 190-196
An abstract:
A ligand-contg. porous membrane was prepd. by radiation-induced graft polymn. of an epoxy-group-contg. monomer of glycidyl methacrylate onto a polyethylene porous hollow-fiber membrane and by subsequent conversion of the epoxy group to an N-methylglucamino (NMG) group at a d. of 0.78 mmol/g of the membrane. Sb(V) soln. was permeated through the NMG-ligand-contg. porous hollow-fiber membrane. Optimum pH for Sb(V) recovery was 3.0. Breakthrough curves of Sb(V) overlapped irresp. of residence times of Sb(V) in the membrane, due to negligible diffusional mass-transfer resistance. Maximum amt. of Sb(V) adsorbed was 130 mg/g-membrane, which was equiv. to 1.3 binding molar ratio. Repeated usage of the membrane for adsorption and elution was possible.


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