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Gibbs free energy expression for the system polystyrene in methylcyclohexane and its application to microencapsulation

発表形態:
原著論文
主要業績:
主要業績
単著・共著:
共著
発表年月:
2003年
DOI:
会議属性:
指定なし
査読:
有り
リンク情報:

日本語フィールド

著者:
Narita, T., Yamamoto, T., Hosoya, E., Dobashi, T.
題名:
Gibbs free energy expression for the system polystyrene in methylcyclohexane and its application to microencapsulation
発表情報:
Langmuir 巻: 19 号: 13 ページ: 5240-5245
キーワード:
概要:
抄録:
A semiempirical equation of Gibbs free energy of mixing ΔG for the system polystyrene in methylcyclohexane has been determined based on the Flory-Huggins equation by using a series of coexistence curve data. The functional form of the interaction parameter g with respect to chain length of the polymer was determined so as to express the critical universality. The resultant equation of ΔG was used to prepare microcapsules of controlled size distribution by means of coacervation in the spinodal region.

英語フィールド

Author:
Narita, T., Yamamoto, T., Hosoya, E., Dobashi, T.
Title:
Gibbs free energy expression for the system polystyrene in methylcyclohexane and its application to microencapsulation
Announcement information:
Langmuir Vol: 19 Issue: 13 Page: 5240-5245
An abstract:
A semiempirical equation of Gibbs free energy of mixing ΔG for the system polystyrene in methylcyclohexane has been determined based on the Flory-Huggins equation by using a series of coexistence curve data. The functional form of the interaction parameter g with respect to chain length of the polymer was determined so as to express the critical universality. The resultant equation of ΔG was used to prepare microcapsules of controlled size distribution by means of coacervation in the spinodal region.


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