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Volume Change of Microcapsules Induced by Solvent Exchange

発表形態:
原著論文
主要業績:
主要業績
単著・共著:
共著
発表年月:
2007年
DOI:
会議属性:
指定なし
査読:
有り
リンク情報:

日本語フィールド

著者:
N. Mogami, S. Lin, T. Narita, Y. Maki, T. Yamamoto and T. Dobashi
題名:
Volume Change of Microcapsules Induced by Solvent Exchange
発表情報:
Transactions of the Materials Research Society of Japan 巻: 32 ページ: 787-890
キーワード:
概要:
抄録:
We have measured volume change of microcapsules composed of dioctylphthalate inner core and polyethyleneglycol-grafted poly(ureaurethane) (PUU) wall membrane induced by solvent exchange in dispersing medium from water to ethanol. The time course of the process consisted of a lag phase, a swelling phase and a shrinking phase. The temperature dependence of the duration of the lag phase tl was roughly described by the Arrhenius plot, and the slope for the logarithm of the time constant vs. the reciprocal of the absolute temperature was coincident with that of the viscosity coefficient of ethanol, suggesting that the permeation rate of ethanol into the core mainly determines the duration of the lag phase.

英語フィールド

Author:
N. Mogami, S. Lin, T. Narita, Y. Maki, T. Yamamoto and T. Dobashi
Title:
Volume Change of Microcapsules Induced by Solvent Exchange
Announcement information:
Transactions of the Materials Research Society of Japan Vol: 32 Page: 787-890
An abstract:
We have measured volume change of microcapsules composed of dioctylphthalate inner core and polyethyleneglycol-grafted poly(ureaurethane) (PUU) wall membrane induced by solvent exchange in dispersing medium from water to ethanol. The time course of the process consisted of a lag phase, a swelling phase and a shrinking phase. The temperature dependence of the duration of the lag phase tl was roughly described by the Arrhenius plot, and the slope for the logarithm of the time constant vs. the reciprocal of the absolute temperature was coincident with that of the viscosity coefficient of ethanol, suggesting that the permeation rate of ethanol into the core mainly determines the duration of the lag phase.


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