日本語フィールド
著者：Fumiya Kanegae, Ko Yoneda , and Masayuki Koikawa題名：Crystal Structure of Dichloro{2-(quinolin-2-yl)-4H-benzo[d][1,3]oxazine}cobalt(II)発表情報：X-ray Structure Analysis Online 巻: 38 ページ: 13キーワード：概要：抄録：The title compound, [CoCl2(qboz)], [qboz = 2-(quinolin-2-yl)-4H-benzo[d][1,3]oxazine], was synthesized and characterized by single-crystal X-ray analysis. This compound crystallizes in the triclinic space group with cell parameters of a = 7.996(5)Å, b = 8.580(6)Å, c = 12.508(8)Å, = 99.154(11)°, = 93.012(11)°, = 108.108(8)°, V = 800.5(9)Å3, Dcalcd = 1.618 g/cm3, Z = 2. The R1 [I > 2(I)] and wR2 (all data) values are 0.0345 and 0.0875, respectively, for all 3549 independent reflections. The benzoxazine ligand is believed to have been obtained by the nucleophilic addition of benzyl alcohol to imine carbon and the subsequent metal-catalyzed air oxidation of the Schiff-base ligand.
(Received August 27, 2021; Accepted September 22, 2021; Published on web January 10, 2022)英語フィールド
Author：Fumiya Kanegae, Ko Yoneda , and Masayuki KoikawaTitle：Crystal Structure of Dichloro{2-(quinolin-2-yl)-4H-benzo[d][1,3]oxazine}cobalt(II)Announcement information:X-ray Structure Analysis Online Vol: 38 Page: 13An abstract：The title compound, [CoCl2(qboz)], [qboz = 2-(quinolin-2-yl)-4H-benzo[d][1,3]oxazine], was synthesized and characterized by single-crystal X-ray analysis. This compound crystallizes in the triclinic space group with cell parameters of a = 7.996(5)Å, b = 8.580(6)Å, c = 12.508(8)Å, = 99.154(11)°, = 93.012(11)°, = 108.108(8)°, V = 800.5(9)Å3, Dcalcd = 1.618 g/cm3, Z = 2. The R1 [I > 2(I)] and wR2 (all data) values are 0.0345 and 0.0875, respectively, for all 3549 independent reflections. The benzoxazine ligand is believed to have been obtained by the nucleophilic addition of benzyl alcohol to imine carbon and the subsequent metal-catalyzed air oxidation of the Schiff-base ligand.
(Received August 27, 2021; Accepted September 22, 2021; Published on web January 10, 2022)