日本語フィールド
著者：Naoko Sato, Ko Yoneda , Yasunori Yamada, and Masayuki Koikawa題名：Synthesis and Crystal Structure of a Mononuclear Cobalt(III) Complex with 2-[(2-Hydroxymethylphenyl)iminomethyl]phenol and Dimethylaminopyridine発表情報：X-ran Structure Analysis Online 巻: 38 ページ: 1キーワード：概要：抄録：A mononuclear cobalt(III) complex with 2-[(2-hydroxymethylphenyl)iminomethyl]phenol (H2L1-H) and dimethylaminopyridine (dmpa), [Co(L1-H)(HL1-H)dmpa]CH3CN, was synthesized and characterized by single-crystal X-ray analysis. The compound crystallizes in the monoclinic space group P21/n (#14) with cell parameters a = 10.551(2)Å, b = 12.499(3)Å, c = 24.242(6)Å, = 92.004(4)°, V = 3194.8(12)Å3, Dcalcd = 1.400 g/cm3, Z = 4. The R1 [I > 2(I)] and wR2 (all data) values are 0.0483 and 0.1226, respectively, for all 7112 independent reflections. The coordination forms of the two H2L1-H ligands are dianionic tridentate and monoanionic bidentate, respectively.英語フィールド
Author：Naoko Sato, Ko Yoneda , Yasunori Yamada, and Masayuki KoikawaTitle：Synthesis and Crystal Structure of a Mononuclear Cobalt(III) Complex with 2-[(2-Hydroxymethylphenyl)iminomethyl]phenol and DimethylaminopyridineAnnouncement information:X-ran Structure Analysis Online Vol: 38 Page: 1An abstract：A mononuclear cobalt(III) complex with 2-[(2-hydroxymethylphenyl)iminomethyl]phenol (H2L1-H) and dimethylaminopyridine (dmpa), [Co(L1-H)(HL1-H)dmpa]CH3CN, was synthesized and characterized by single-crystal X-ray analysis. The compound crystallizes in the monoclinic space group P21/n (#14) with cell parameters a = 10.551(2)Å, b = 12.499(3)Å, c = 24.242(6)Å, = 92.004(4)°, V = 3194.8(12)Å3, Dcalcd = 1.400 g/cm3, Z = 4. The R1 [I > 2(I)] and wR2 (all data) values are 0.0483 and 0.1226, respectively, for all 7112 independent reflections. The coordination forms of the two H2L1-H ligands are dianionic tridentate and monoanionic bidentate, respectively.