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Synthesis and Crystal Structure of Bis{2-[(2-hydroxymethylphenyl)iminomethyl]-4-nitro-phenolato}nickel(II) Monoacetonitrile

発表形態:
原著論文
主要業績:
主要業績
単著・共著:
共著
発表年月:
2021年12月
DOI:
会議属性:
指定なし
査読:
有り
リンク情報:

日本語フィールド

著者:
Yuka Mineyama, Ko Yoneda , Yasunori Yamada, and Masayuki Koikawa
題名:
Synthesis and Crystal Structure of Bis{2-[(2-hydroxymethylphenyl)iminomethyl]-4-nitro-phenolato}nickel(II) Monoacetonitrile
発表情報:
X-ray Structure Analysis Online 巻: 37 ページ: 85
キーワード:
概要:
抄録:
The title compound, [Ni(HL1-NO2)2]CH3CN, [H2L1-NO2 = 2-[2-(hydroxymethylphenyl)iminomethyl]-4-nitrophenol], was synthesized and characterized by single-crystal X-ray analysis. The compound crystallizes in the triclinic space group P\bar{1} with cell parameters a = 10.556(2)Å, b = 11.779(3)Å, c = 12.247(3)Å,  = 86.412(10)°,  = 71.135(8)°,  = 73.009(8)°, V = 1377.2(5)Å3, Dcalcd = 1.549 g/cm3, Z = 2. The R1 [I > 2(I)] and wR2 (all data) values are 0.0362 and 0.1024, respectively, for all 5989 independent reflections. The tridentate ligands coordinate to the nickel atom as a mer-manner.

英語フィールド

Author:
Yuka Mineyama, Ko Yoneda , Yasunori Yamada, and Masayuki Koikawa
Title:
Synthesis and Crystal Structure of Bis{2-[(2-hydroxymethylphenyl)iminomethyl]-4-nitro-phenolato}nickel(II) Monoacetonitrile
Announcement information:
X-ray Structure Analysis Online Vol: 37 Page: 85
An abstract:
The title compound, [Ni(HL1-NO2)2]CH3CN, [H2L1-NO2 = 2-[2-(hydroxymethylphenyl)iminomethyl]-4-nitrophenol], was synthesized and characterized by single-crystal X-ray analysis. The compound crystallizes in the triclinic space group P\bar{1} with cell parameters a = 10.556(2)Å, b = 11.779(3)Å, c = 12.247(3)Å,  = 86.412(10)°,  = 71.135(8)°,  = 73.009(8)°, V = 1377.2(5)Å3, Dcalcd = 1.549 g/cm3, Z = 2. The R1 [I > 2(I)] and wR2 (all data) values are 0.0362 and 0.1024, respectively, for all 5989 independent reflections. The tridentate ligands coordinate to the nickel atom as a mer-manner.


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