日本語フィールド
著者：Shohei Yamamoto, Ryoji Mitsuhashi, Masahiro Mikuriya, Masayuki Koikawa, Hiroshi Sakiyama題名：Crystal structure, magnetic properties, and structural prediction for an oxidovanadium(IV) complex [VO(dmf)5][PF6]2発表情報： 巻: 74 号: 8 ページ: 1222-1232キーワード：概要：抄録：Pentakis(dimethylformamide-jO)oxidovanadium(IV) bis(hexafluoridophosphate), [VO(dmf)5][PF6]2 (dmf: dimethylformamide), was synthesized, and its crystal structure was revealed by a singlecrystal X-ray method. The [VO(dmf)5]2þ complex cation dimerized in the crystal, and a weak ferromagnetic interaction was attributed to the dimerized structure. In addition, conformational prediction was successfully conducted using the enumeration result on the basis of group theory. As a result, a reasonable monomer structure of the defect-S6 symmetry was obtained as the most stable structure in dilute solution; in addition, a dimer structure was predicted as the structure in a crystal. (https://doi.org/10.1080/00958972.2021.1890049)英語フィールド
Author：Shohei Yamamoto, Ryoji Mitsuhashi, Masahiro Mikuriya, Masayuki Koikawa, Hiroshi SakiyamaTitle：Crystal structure, magnetic properties, and structural prediction for an oxidovanadium(IV) complex [VO(dmf)5][PF6]2Announcement information: Vol: 74 Issue: 8 Page: 1222-1232An abstract：Pentakis(dimethylformamide-jO)oxidovanadium(IV) bis(hexafluoridophosphate), [VO(dmf)5][PF6]2 (dmf: dimethylformamide), was synthesized, and its crystal structure was revealed by a singlecrystal X-ray method. The [VO(dmf)5]2þ complex cation dimerized in the crystal, and a weak ferromagnetic interaction was attributed to the dimerized structure. In addition, conformational prediction was successfully conducted using the enumeration result on the basis of group theory. As a result, a reasonable monomer structure of the defect-S6 symmetry was obtained as the most stable structure in dilute solution; in addition, a dimer structure was predicted as the structure in a crystal. (https://doi.org/10.1080/00958972.2021.1890049)